乙炔、乙烯、乙烷的色谱分离是气相色谱(GC)中的一个经典课题。这三种气体性质相似,但通过合理选择色谱柱和条件,可以实现高效分离。
分离难点
沸点接近:乙烷(-88.6°C)、乙烯(-103.7°C)、乙炔(-84°C)沸点都非常低,且相差不大,仅靠沸点差异(分配作用)分离效果不佳。
性质差异关键:它们的极性和不饱和度不同。
乙烷:非极性饱和烃。
乙烯:弱极性(π键),不饱和烯烃。
乙炔:线性分子,极性最强(碳碳三键),且酸性最强(氢原子略带酸性)
浩瀚色谱(山东)应用技术开发有限公司,研制《乙烯乙烷乙炔的测定毛细管色谱柱应用岛津,可以清晰、完全地分离乙烷、乙烯和乙炔,并进行准确的定量分析。
名称:毛细管柱
固定相:专用
规格:30mm*0.32mm
型号:HH-C2-30
应用:乙烯,乙烷,乙炔的色谱分离
应用:
安捷伦490在线/便携,4890,5890,6890,7820,7890,8860,8890
岛津GC-14C,GC-2010,GC-2014,GC-2030
赛默飞1310,1300,1610,1600
瓦里安3800系列
布鲁克PE580,590,680,690
磐诺A90,福立GC9790,华爱,天瑞,天美,GC7900,川仪,北分瑞利,东西电子,鲁南瑞虹,捷岛/科晓


The chromatographic separation of acetylene, ethylene, and ethane is a classic topic in gas chromatography (GC). These three gases have similar properties, but efficient separation can be achieved through reasonable selection of chromatographic columns and conditions.
Difficulty in Separation
Boiling point proximity: Ethane (-88.6 ° C), ethylene (-103.7 ° C), and acetylene (-84 ° C) all have very low boiling points, and the difference is not significant. The separation effect is not good solely based on boiling point differences (distribution effect).
The key difference in properties is their polarity and unsaturation.
Ethane: non-polar saturated hydrocarbon.
Ethylene: weakly polar (π - bond), unsaturated olefin.
Acetylene: a linear molecule with the strongest polarity (carbon carbon triple bond) and the strongest acidity (hydrogen atom slightly acidic)
Haohan Chromatography (Shandong) Application Technology Development Co., Ltd. has developed a capillary chromatography column for the determination of ethylene, ethane, and acetylene using Shimadzu, which can clearly and completely separate ethane, ethylene, and acetylene, and perform accurate quantitative analysis.
Name: Capillary Column
Fixed phase: Dedicated
Specification: 30mm * 0.32mm
Model: HH-C2-30
Application: Chromatographic separation of ethylene, ethane, and acetylene
Application:
Agilent 490 online/portable, 48905890689088608890
Shimadzu GC-14C, GC-2010, GC-2014, GC-2030
Thermo Fisher Scientific 1310130016101600
Varian 3800 Series
Brooke PE580590680690
Panno A90, Fuli GC9790, Huaai, Tianrui, Tianmei, GC7900, Chuanyi, Beifen Ruili, Dongxi Electronics, Lunan Ruihong, Jiedao/Kexiao
滕州市浩瀚色谱仪器技术服务有限公司
电话:0632-5667636
传真:0632-5667636
手机:15562228838,13963221227
地址:山东滕州市平行路(商务部和技术部)
邮箱:wangxiaoying9@126.com
QQ:1404939462
联系人:王经理
网址:www.haohansepu.com