恶臭硫化物的色谱测定是一个技术要求高、需要高度关注细节的分析领域。成功的关键在于：
选择合适的色谱柱和检测器： FPD/PFPD/SCD是气体样品的主流；极性柱+SCD/MSD常用于液体或衍生化样品。
使用高度惰性的采样和前处理系统： 吸附管采样-热脱附（气体）、吹扫捕集（水样）是最常用且灵敏的富集方法。所有接触面必须惰性化。
严格控制样品保存和操作条件： 避免吸附、氧化、光解、污染。
建立准确可靠的校准方法： 推荐使用外标法或内标法，标准曲线需覆盖预期浓度范围，并包含前处理步骤。
遵循相关标准方法并严格进行质量控制： 包括空白实验、平行样、加标回收率等。
通过精心设计和严格控制整个分析流程，气相色谱法能够准确、灵敏地测定环境介质和工业过程中的恶臭硫化物，为污染控制、工艺优化和质量监控提供关键数据。
浩瀚色谱(山东)应用技术开发有限公司，采用HH-S3硫专用柱火焰光度检测器气相色谱法测定环境空气中硫化氢、甲硫醇、甲硫醚、二硫化碳、二甲二硫、噻吩等6种硫化物,讨论了采样容器材质的影响。方法线性良好,6种硫化物的检出限为1.1μg/m3～5.1μg/m3,混合标准气平行测定的RSD≤8.5%,
名称：硫化物测定专用柱
型号：HH一S3
规格：3m*3mm
材质：聚四氟乙烯
zui高使用温度：120°C
应用：GB/T 14678-1993空气质量 硫化氢、甲硫醇、甲硫醚和二甲二硫的测定 气相色谱法
适用于：
安捷伦490在线/便携，4890,5890,6890,7820,7890,8860,8890
岛津GC-14C，GC-2010，GC-2014，GC-2030
赛默飞1310,1300,1610,1600
瓦里安3800系列
布鲁克PE580,590,680,690
磐诺A90，福立GC9790，华爱，天瑞，天美，GC7900，川仪，北分瑞利，东西电子，鲁南瑞虹，捷岛/科晓
The chromatographic determination of odorous sulfides is an analytical field that requires high technical requirements and attention to detail. The key to success lies in:
Choose appropriate chromatographic columns and detectors: FPD/PFPD/SCD are the mainstream for gas samples; Polar columns+SCD/MSD are commonly used for liquid or derivatized samples.
The use of highly inert sampling and pretreatment systems: adsorption tube sampling thermal desorption (gas), blowdown capture (water sample) are the most commonly used and sensitive enrichment methods. All contact surfaces must be inert.
Strictly control sample storage and operating conditions: avoid adsorption, oxidation, photolysis, and contamination.
Establish accurate and reliable calibration methods: It is recommended to use external or internal standard methods, and the standard curve should cover the expected concentration range and include pre-processing steps.
Follow relevant standard methods and strictly control quality, including blank experiments, parallel samples, spiked recovery rates, etc.
By carefully designing and strictly controlling the entire analysis process, gas chromatography can accurately and sensitively determine odorous sulfides in environmental media and industrial processes, providing key data for pollution control, process optimization, and quality monitoring.
Haohan Chromatography (Shandong) Application Technology Development Co., Ltd. used HH-S3 sulfur specific column flame photometric detector gas chromatography to determine six types of sulfides in ambient air, including hydrogen sulfide, methyl mercaptan, methyl sulfide, carbon disulfide, dimethyl disulfide, thiophene, etc. The influence of sampling container material was discussed. The method has good linearity, with detection limits of 1.1 μ g/m3 to 5.1 μ g/m3 for 6 sulfides, and RSD ≤ 8.5% for parallel determination of mixed standard gas,
Name: Special Column for Sulfide Determination
Model: HH-S3
Specification: 3m * 3mm
Material: Polytetrafluoroethylene
Maximum operating temperature: 120 ° C
Application: GB/T 14678-1993 Air quality - Determination of hydrogen sulfide, methyl mercaptan, methyl sulfide and dimethyl disulfide - Gas chromatographic method
Suitable for:
Agilent 490 online/portable, 48905890689088608890
Shimadzu GC-14C, GC-2010, GC-2014, GC-2030
Thermo Fisher Scientific 1310130016101600
Varian 3800 Series
Brooke PE580590680690
Panno A90, Fuli GC9790, Huaai, Tianrui, Tianmei, GC7900， Chuanyi, Beifen Ruili, Dongxi Electronics, Lunan Ruihong, Jiedao/Kexiao
滕州市浩瀚色谱仪器技术服务有限公司
电话：0632-5667636
传真：0632-5667636
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